Well, one issue is the question whether or not this girl even know that you're interested in girls yourself. If she isn't, she might not have even seen you as a possible partner to begin with.
Either way, simply getting to know her is a good way to start. Talk, show your interest a bit, pay attention to her behaviour and see if interest is returned. Body language is useful like that. If she doesn't return any romantic interest, try cultivating a regular friendship instead. It never hurts to have a friendly face with similar interests.